Amphiboles: Crystal Chemistry, Occurrence, and Health Issues by Frank C. Hawthorne, Roberta Oberti, Giancarlo Della Ventura,

By Frank C. Hawthorne, Roberta Oberti, Giancarlo Della Ventura, Annibale Mottana

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Extra resources for Amphiboles: Crystal Chemistry, Occurrence, and Health Issues (Reviews in Mineralogy and Geochemistry 67)

Sample text

3 M(4) (A) (Å) Figure 26. Variation in the β angle in as a function of the aggregate radius of the M(4) cations for selected C2/m amphiboles. Table 8. Regression results for the M(4)-sites in C2/m amphiboles and [6]M4 in Pnma amphiboles. 363(74) * s = standard error of estimate. 26 ½, and in calcic, sodic-calcic and sodic amphiboles with a signiicant component of B(Mg, Fe, Mn), both sites can be identiied (Rossi et al. 1987; Oberti and Ghose 1993). A detailed discussion of the coordination at the M(4) site is given by Hawthorne (1983a).

930) is justiied by its far smaller variance. 4 Å3. They are consistent with those extrapolated by Gottschalk et al. 3 Å3. It is not easy to interpret the relative importance of the various chemical descriptors on the variation of the dependent variable because the regression coeficient must be weighted for the possible abundance of each cation/anion. For the a edge, the key role is played by A K and by the incorporation of highly charged cations at the M(1,2,3) sites. However, each (b) (a) Figure 35.

1987; Castelli 1988; Morrison 1991; Enami et al. 1992; Zhu et al. 1994; Kullerud 1996; Leger et al. 1996; Sato et al. 1997; McCormick and McDonald 1999), indicating the effect of increasing Fe2+ in increasing the dimensions of the strip of octahedra, and increasing K promoting the bonding between K at the A(m) site and Cl at O(3) (see also Oberti et al. 2007b). O(3) = O. The occurrence of O at O(3) places considerable restrictions on occupancy of the adjacent M(1) and M(3) sites as the bond-valence requirements of the oxygen atom at O(3) must be satisied by the three adjacent M(1) and M(3) cations.

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